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EEJ MAIN Chemistry QUESTION #1018
Question 1
The most stable carbocation from the following is:
  • Benzyl carbocation \((\text{PhCH}_2^+)\) without additional substituent
  • Benzyl carbocation with \(-\text{OMe}\) at para position (electron-donating)
  • Benzyl carbocation with \(-\text{OMe}\) at meta position✔️
  • Benzyl carbocation with \(-\text{CH}_3\) at para position
Correct Answer Explanation
Carbocation stability increases with electron-donating groups at ortho/para positions via resonance. A \(-\text{OMe}\) group at the para position donates electrons by resonance directly into the carbocation centre, making it the most stable. Meta substitution cannot relay resonance to the positive charge.