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CSS Physical and Inorganic Chemistry P-I QUESTION #1423
Question 1
In solvent extraction, the distribution coefficient is:
  • Ratio of solute concentration in two phases✔️
  • Ratio of solvents used
  • Ratio of extractant to sample volume
  • None of these
Correct Answer Explanation
The distribution coefficient (partition coefficient) \(K_D\) in solvent extraction is defined as: \(K_D = \dfrac{[\text{solute}]_{\text{organic}}}{[\text{solute}]_{\text{aqueous}}}\) — the ratio of the concentration of solute in the organic (extracting) phase to its concentration in the aqueous phase at equilibrium. A high \(K_D\) means preferential distribution into the organic phase.