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SSC Organic and Environmental Chemistry P-II QUESTION #1448
Question 1
The resonance energy of benzene is approximately:
  • 150 kJ/mol✔️
  • 200 kJ/mol
  • 250 kJ/mol
  • None of these
Correct Answer Explanation
The resonance (delocalisation) energy of benzene is approximately 150 kJ/mol (about 36 kcal/mol). This is experimentally determined by comparing the actual heat of hydrogenation of benzene (~208 kJ/mol) with the theoretical value calculated for a hypothetical cyclohexatriene (~360 kJ/mol). The difference (~150 kJ/mol) represents the extra stability due to aromatic delocalisation.