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JEE MAIN Chemistry QUESTION #5546
Question 1
Which of the following substances exists as a covalent crystal (network solid) in the solid state?
  • Iodine
  • Silicon✔️
  • Sulphur
  • Phosphorus
Correct Answer Explanation
Silicon forms a giant covalent (network) crystal similar to diamond, where each Si atom is covalently bonded to four others in a tetrahedral arrangement extending throughout the crystal. This gives it a very high melting point. Iodine forms molecular crystals, sulphur and phosphorus also form molecular crystals.