Home MCQs EEJ MAIN Chemistry Question #5576
Back to Questions
EEJ MAIN Chemistry QUESTION #5576
Question 1
The strongest acid among the following compounds is:
  • HCOOH (formic acid)
  • $CH_3CH_2CH(Cl)CO_2H$ (2-chlorobutanoic acid)✔️
  • $ClCH_2CH_2CH_2COOH$ (4-chlorobutanoic acid)
  • $CH_3COOH$ (acetic acid)
Correct Answer Explanation
Acid strength increases with electron-withdrawing inductive effect of substituents closer to the –COOH group. In option B, Cl is at the $\alpha$-carbon (adjacent to –COOH), providing maximum inductive withdrawal. In option C, Cl is at the $\gamma$-position (far from –COOH), with much weaker inductive effect. Formic acid (A) is stronger than acetic acid (D) but weaker than $\alpha$-chloro acid.