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EEJ MAIN Chemistry QUESTION #7147
Question 1
Among the following alkaline earth metal sulfates, which one possesses a hydration enthalpy that is greater than its lattice enthalpy?
  • $CaSO_{4}$
  • $BeSO_{4}$✔️
  • $BaSO_{4}$
  • $SrSO_{4}$
Correct Answer Explanation
Solubility of sulfates depends on the balance between lattice energy and hydration energy. As we move down the group, both decrease, but lattice energy decreases slowly due to the large size of the sulfate ion. However, $Be^{2+}$ is exceptionally small, giving it a very high hydration enthalpy that exceeds its lattice enthalpy, making $BeSO_{4}$ highly soluble.