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EEJ MAIN Chemistry QUESTION #7149
Question 1
Which of the following alkaline earth metal nitrates does not contain water of crystallization in its solid form?
  • $Mg(NO_{3})_{2}$
  • $Sr(NO_{3})_{2}$
  • $Ca(NO_{3})_{2}$
  • $Ba(NO_{3})_{2}$✔️
Correct Answer Explanation
The ability of alkaline earth metal ions to hydrate decreases as the size of the cation increases. Barium ($Ba^{2+}$) has the largest size and lowest charge density among the options provided, meaning it does not have enough polarizing power to hold water molecules. Consequently, $Ba(NO_{3})_{2}$ crystallizes as an anhydrous salt.