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NEET Chemistry QUESTION #7394
Question 1
Four successive first-row transition elements are listed with their atomic numbers. Which is expected to have the highest third ionisation enthalpy?
  • Vanadium (Z = 23)
  • Manganese (Z = 25)āœ”ļø
  • Chromium (Z = 24)
  • Iron (Z = 26)
Correct Answer Explanation
Third ionisation involves removing the 3rd electron.

Mn (Z=25): configuration [Ar] 3d⁵ 4s². After losing 2e⁻ → [Ar] 3d⁵ (half-filled, very stable). Removing the 3rd electron from a half-filled 3d⁵ shell requires breaking extra stability — very high energy needed.

Therefore, Mn has the highest third ionisation enthalpy among these elements.