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Mn (Z=25): configuration [Ar] 3dโต 4sยฒ. After losing 2eโป โ [Ar] 3dโต (half-filled, very stable). Removing the 3rd electron from a half-filled 3dโต shell requires breaking extra stability โ very high energy needed.
Therefore, Mn has the highest third ionisation enthalpy among these elements.
The development of broadcast regulation in the U.S. followed a logical progression:
- Early radio (post-1920): Anyone could build and operate a radio station, leading to hundreds of unlicensed stations fighting for limited frequencies and even engaging in “power wars” to drown out competitors
- Radio Act of 1927: Created the Federal Radio Commission (FRC) to organise the licensing of transmitters and assign radio station frequencies
- Communications Act of 1934: Reorganised the FRC into the Federal Communications Commission (FCC), which expanded regulatory authority to include telephone and telegraph as well as broadcasting
The driving force behind regulation was the entry of commercial advertising money and corporate interests โ once radio became profitable, the government had strong incentives to impose order. The FCC's regulatory powers later expanded to include television.
Naegele's Rule formula:
\[\text{EDD} = \text{LMP} - 3\,\text{months} + 7\,\text{days} + 1\,\text{year}\]
Or equivalently: Add 9 months and 7 days to LMP
Calculation:
- LMP: 10th September
- Subtract 3 months: 10th June
- Add 7 days: 17th June
- Add 1 year (next year)
Therefore, EDD = 17th June (next year)
Normal pregnancy duration: \(280\,\text{days}\) or \(40\,\text{weeks}\) from LMP \(= 266\,\text{days}\) from conception.
Important caveat: Naegele's rule assumes a regular 28-day cycle with ovulation on Day 14. Adjust for irregular cycles accordingly. Ultrasound (especially first trimester CRL) is more accurate for dating.
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